7 October 2005

Are you Ready for Lead-Free Solder?

Major changes will soon affect nearly everyone who makes or uses electronic equipment, including amateur scientists. The changes are a result of serious concerns about the toxicity of certain materials used in the manufacture of electronic components and equipment. Fluorescent tubes contain mercury. Electronic circuit boards and the glass used to make cathode ray tubes contain lead. Various electronic components and batteries contain cadmium.

The European Union has passed a directive that effectively bans many materials commonly used to manufacture electronic components and systems. Because of the international nature of electronics commerce, the ban will affect many countries outside the European Union.

There is good reason to be concerned about the sweeping nature of the ban. For example, cadmium sulfide photoresistors are used as light sensors in a wide variety of applications. Cadmium sulfide is also used to make solar cells. Nickel cadmium rechargeable batteries contain cadmium. Cadmium coatings provide important corrosion resistance for various electronic components. Yet the EU directive effectively bans these and other applications for cadmium and various other materials: "Member States shall ensure that, from 1 July 2006, new electrical and electronic equipment put on the market does not contain lead, mercury, cadmium, hexavalent chromium, polybrominated biphenyls (PBB) or polybrominated diphenyl ethers (PBDE)."

The ban on lead will have an especially broad impact. Consider the solder that secures electronic components to circuit boards and provides mechanical strength and excellent electrical conductivity.

The impact on the ban on lead in solder has been addressed by Dr. Craig Hillman of DfR Solutions in "Long-term reliability of Pb-free electronics" in Electronic Products magazine. The subtitle of Dr. Hillman's article is, "Will the field return rate of your product be going up after Pb-free conversion?" Figure 1 illustrates the importance of this question, for traditional tin-lead solder provides significant mechanical shock resistance for electronic circuit boards. Switching to non-lead solder may greatly reduce the long-term reliability of electronic systems.

Dr. Hillman also discusses other problems with lead-free solder, including the formation of tin whiskers that can caused short circuits between conductors on circuit boards.

Amateur scientists can learn more about the coming ban on many common electronic materials by visiting the compliance page at the Newark Electronics web site. This site features many relevant links. Especially important is the link to the latest 2005 exemptions. This site lists new exemptions and those under appeal. Note the request to exempt cadmium sulfide photocells.

Citizen scientists are invited to send comments about this issue to "Backscatter." Please type "Lead Ban" in the subject line.

Forrest M. Mims III


 

Figure 1. Lead-free solder joints are more likely to fail when subjected to vibration or shock than joints formed from a lead-tin alloy. This photograph shows a failure in a lead-free solder connection. Courtesy DfR Solutions.

   
Copyright 2005 by Society for Amateur Scientists